T.A. Yasnygina1, S.V. Rasskazov1,2, E.P. Chebykin1,3, T.S. Fileva1, E.V. Saranina1,4, Yi-min Sun5
1Institute of the Earth's Crust SB RAS, Irkutsk, Russia
2Irkutsk State University, Irkutsk, Russia
3Limnological Institute SB RAS, Irkutsk, Russia
4A.P. Vinogradov Institute of Geochemistry SB RAS, Irkutsk, Russia
5Institute of Natural Resources and Ecology of Heilongjiang Academy of Sciences, Harbin, China
Yasnygina Tatyana Aleksandrovna,
Candidate of Geological and Mineralogical Sciences, Senior Researcher
664033 Irkutsk, Lermontov str., 128,
Institute of the Earth's Crust SB RAS,
email: ty@crust.irk.ru.
Rasskazov Sergey Vasilyevich,
Doctor of Geological and Mineralogical Sciences, Professor, Head of the Laboratory, Head of the Department,
664033 Irkutsk, Lermontov str., 128,
Institute of the Earth's Crust SB RAS,
664003 Irkutsk, Lenin str., 3,
Irkutsk State University, Faculty of Geology,
email: rassk@crust.irk.ru.
Chebykin Evgeny Pavlovich,
Candidate of Chemical Sciences, Senior Researcher,
664033 Irkutsk, Lermontov str., 128,
Institute of the Earth's Crust SB RAS,
664033 Irkutsk, Ulaanbaatarskaya str., 3,
Limnological Institute SB RAS,
email: epcheb@yandex.ru.
Fileva Tatyana Semenovna,
Lead Engineer,
664033 Irkutsk, Lermontov str., 128,
Institute of the Earth's Crust SB RAS.
Saranina Elena Vladimirovna,
Candidate of Geological and Mineralogical Sciences, Leading Engineer,
664033 Irkutsk, Lermontov str., 128,
Institute of the Earth's Crust SB RAS,
664033 Irkutsk, Favorskogo str., 1a,
A.P. Vinogradov Institute of Geochemistry SB RAS,
email: e_v_sar@mail.ru.
Sun Yi-min,
Research Fellow,
Institute of Natural Resources and Ecology, Heilongjiang Academy of Sciences, Harbin, China,
email: 894817259@qq.com.
Abstract. IIn therapeutic mud (peloids) of Lake Nuhu Nur, major oxides, trace elements, and mineral phases are determined from sedimentary columns taken in the central and near-coastal parts of the lake. In the center of the lake, layers with high and low contents of total sulfur (Stot) and S2− alternate. Sulfur is part of sulfates: gypsum, tenardite, and hexahydrite. The distribution of S is generally correlated with Na2O, CaO, Sr, and U with a strong negative correlation with other major oxides and trace elements. In near-coastal parts of the lake, there are layers enriched and depleted with CaO, which strongly correlates with Sr. Lithogeochemical signatures of peloids show concentration of therapeutic components in the bottom sediments of the lake due to processes similar to weathering of rocks of silicic composition in arid climate. In terms of major oxides and trace elements, peloids from Lake Nuhu Nur are generally comparable to those from Wudalianchi (Northeast China), coastal regions of Brazil, as well as Georgia and Spain, but are closest to therapeutic high-sulfur sulfate mud of Kopahue in Argentina.
Keywords: peloids, therapeutic mud, ICP-MS, major oxides, trace elements, sulfur, sulfides, sulfates.
P. 84–109
Bokuchava N. Therapeutic mud of Georgia. Tbilisi: Publishing House "Technical University", 2009. 157 p.
Vikulova M.F., Burkov Yu.K., Makedonov A.V., Tikhomirova N.Ya., Osipova A.I., Feofilova A.P., Kulakova G.V., Zemova N.N. Facial types of clay rocks and their primary lithological features. Leningad: Nedra, 1973. 288 p.
Gaskova O.L., Solotchina E.P., Sklyarova O.A. Reconstruction of the evolution of the composition of solutions according to the sedimentary chronicle of salt lakes of Priolkhonya // Geology and Geophysics 2011. Vol. 52, No. 5. P. 704–711.
Zavarzin G.A., Kolotilova N.N. Introduction to natural history microbiology. Moscow: Knizhnyi dom «University», 2001. 256 p.
Krutikova A.I., Kaurov V.F. Mineral water of the north-eastern part of the Kuda Basin // Mineral water of Eastern Siberia. Moscow: Publisher of AS USSR, 1963. P. 89–95.
Criteria for assessing the quality of therapeutic mud during their exploration, use, and protection. Methodical instructions: approved by the Ministry of Health of the USSR on 11.03.1987 No. 10-11/40. Moscow: Ministry of health of USSR, 1987. 24 p.
Leonova G.A., Maltsev A.E., Melenevsky V.N., Miroshnichenko L.V., Kondratyeva L.M., Bobrov V.A. Geochemistry of diagenesis of organogenic sediments on the example of small lakes of the south of Western Siberia and the Baikal region // Geochemistry. 2018. Vol. 56, No. 4. P. 363–382. doi: 10.7868/S0016752518030068
Namsaraev B.B., Khakhinov V.V., Garmaev E.Zh., Barkhutova D.D., Namsaraev Z.B., Plyusnin A.M. Water systems of the Barguzin basin. Ulan-Ude: Publisher of Buryat State University, 2007. 154 p.
Rasskazov S.V., Xie J., Sun Y., Yasnygina T.A., Chuvashova I.S. Formation of plastic clays in the gaps of the paleopeloid layer: the probable mechanism of the origin of the source of the mud volcano in the Songliao basin // Rifting, orogeny and accomponied processes. Proceedings of the IV All-Russia Symposium with the participation of foreign scientists, dedicated to the 90th anniversary of the birth of Academician N.A. Logatchev. Irkutsk: Institute of the Earth’s crust SB RAS, 2019. P. 149–151.
Samarina V.S. Hydrogeochemistry. Leningrad: Publisher of Leningrad University, 1977. 360 p.
Sizykh Yu.I. Complex scheme of chemical analysis of rocks and minerals. Report. Irkutsk: Institute of the Earth’s crust SB AS USSR, 1985. 61 p.
Sklyarov E.V., Solotchina E.P., Vologina E.G., Ignatova N.V., Izokh O.P., Kulagina N.V., Sklyarova O.A., Solotchin P.A., Stolpovskaya V.N., Ukhova N.N., Fedorovsky V.S., Khlystov O.M. Detailed chronicle of the Holocene climate from the carbonate section of the salt lake Tsagan-Tyrm (Western Baikal region) // Geology and Geophysics. 2010. Vol. 51, No. 3. P. 303–328.
Solotchina E.P., Sklyarov E.V., Strakhovenko V.D., Solotchin P.A., Sklyarova O.A. Mineralogy and crystal chemistry of carbonates of modern sediments of small lakes Priolkhonya (Baikal region) // Doklady Earth Science. 2015. Vol. 461, No. 5. P. 579–585. doi:10.7868/S0869565215110213
Strakhovenko V.D., Solotchina E.P., Vosel Yu.S., Solotchin P.A. Geochemical factors of autigenic mineral formation in bottom sediments of lakes of the Tazheran system (Pribaikalye) // Geology and Geophysics. 2015. Vol. 56, No. 10. P. 1825–1841. doi:10.15372/GiG20151006
Strakhovenko V.D., Shcherbov B.L., Malikova I.N., Vosel Yu.S. Regularities of distribution of radionuclides and rare earth elements in bottom sediments of Siberian lakes // Geology and Geophysics. 2010. Vol. 51, No. 11. P. 1501–1514.
Stupnikova N.A., Muradov S.V. Physical-chemical and microbiological studies of therapeutic mud deposits Lake Utinoye of the Kamchatka region // Bulletin FEB RAN. 2005, No.3. P. 76–82.
Shpeyzer G.M., Yakovlev T.N., Bekhterev N.V. K gidrohimiki mineralnogo ozera Nuha-Nur // Trudy Irkutskogo gosudarstvennogo universiteta. T. L, ser. Chemical. Vol. 3, ch. II. Irkutsk, 1970. P. 131–136.
Yudovich Y.E., Ketris M.P. Geochemical indicators of lithogenesis (lithological geochemistry). Syktyvkar: Geoprint, 2011. 742 p.
Yasnygina T.A., Rasskazov S.V., Markova M.E., Pakhomova N.N. Determination of rare earth elements, Y, Zr, Nb, Hf, Ta, Th in standard samples of the DV series by mass spectrometry with inductively bound plasma // Zavodskaya laboratory. Diagnostics of materials. 2015. Vol. 81, No. 2. P. 10–20.
Yasnygina T.A., Rasskazov S.V., Chebykin E.P., Saranina E.V., Sun Y. Composition of silt therapeutic mud oz. Nuha-Nur (Bayandaevsky district of the Irkutsk region), comparison with popular therapeutic mud of the world // Rifting, orogeny, and accomponied processes. Proceedings of IV All-Russia Symposium with the participation of foreign scientists, dedicated to the 90th anniversary of the birth of N.A. Logatchev. Irkutsk: Institute of the Earth’s crust SB RAS. P. 260–262.
Baschini M.T., Pettinari G.R., Valles J.M., Aguzzi C., Cerezo P., Lopez-Galindo A., Setti M., Viseras C. Suitability of natural sulphur-rich muds from Copahue (Argentina) for user as semisolid health care products // Applied Clay Sci. 2010. V. 49 (3). P. 205–212. doi:10.1016/j.clay.2010.05.008
Carretero M.I., Pozo M., Martin-Rubi J.A., Pozo E., Maraver F. Mobility of elements in interaction between artificial sweat and peloids used in Spanish spas // Applied Clay Sci. 2010. V. 48. P. 506–515. doi:10.1016/j.clay.2010.02.016
Cox R., Lowe D.R., Cullers R.L. The influence of sediment recycling and basement composition on evolution of mudrock chemistry in southwestern United States // Geochim. et Cosmochim. Acta. 1995. V. 59. P. 2919–2940. doi:10.1016/0016-7037(95)00185-9
Cullers R.L. Implications of elemental concentrations for provenance, redox conditions, and metamorphic studies of shales and limestones near Pueblo, CO, USA // Chem. Geol. 2002. V. 191 (4). P. 305–327. doi:10.1016/S0009-2541(02)00133-X
Da Silva P.S.C., Torricilha J.K., de Macedo Gouvea P.F., Maduar M.F., de Oliveira S.M.B., Scapin M.A. Chemical and radiological characterization of Peruibe Black Mud // Applied Clay
Sci. 2015. V. 118. P. 221–230. doi:10.1016/j.clay.2015.09.016
Goldhaber M.B. Sulfur-rich sediments. Sediments, diagenesis, and sedimentary rocks // Treatise on Geochemistry. Elsevier, 2005. V. 7. P. 257–288.
Karakaya M.C., Karakaya N., Sarioglan S., Koral M. Some properties of thermal mud of some spas in Turkey // Applied Clay Sci. 2010. V. 48, P. 531–537. doi:10.1016/j.clay.2010.02.005
Khiari I., Mefteh S., Sanchez-Espejo R., Cerezo P., Aguzzi C., Lopez-Calindo A., Jamoussi F., Iborra C.V. Study of traditional Tunisian medina clays used in therapeutic and cosmetic mud-packs // Applied Clay Sci. 2014. V. 101. P. 141–148. doi:10.1016/j.clay.2014.07.029
Kotova I., Kayukova E., Kotov S. Peloids of Crimean salt lakes and the Dead Sea: controls on composition and formation // Environ Earth Sci. 2016. V. 75, 1207. doi:10.1007/s12665-016-5999-1
McDonough W.F., Sun S.-S. The composition of the Earth // Chem. Geol. 1995. V. 120. P. 223–253. doi:10.1016/0009-2541(94)00140-4
Nesbitt H.W., Young, G.M. Early Proterozoic climates and plate motions inferred from major element chemistry of lutites // Nature 1982. V. 299. P. 715–717.
Rasskazov S.V., Chuvashova I.S., Sun Y., Yang Ch., Xie Zh., Yasnygina T.A., Saranina E.V., Fang Zh. Sources of Quaternary potassic volcanic rocks from Wudalianchi, China: Control by transtension at the lithosphere–asthenosphere boundary layer // Geodynamics & Tectonophysics 2016. V. 7 (4). P. 555–592. doi:10.5800/GT-2016-7-4-0223
Rasskazov S., Xie Z., Yasnygina T., Chuvashova I., Wang X., Arsentev K., Sun Y., Fang Z., Zeng Y. Geochemical and clay-mineral study of healing mud from Wudalianchi, NE China // Geodynamics & Tectonophysics. 2017. V. 8 (3). P. 539–544. doi:10.5800/GT-2017-8-3-0285
Taylor S.R., McLennan S.M. The continental crust: its composition and evolution. Blackwell: Scientific Publications, 1985. 312 р.
Yasnygina T.A. Lithogeochemical signatures of high-sulfur therapeutic mud from Nuhu-Nur Lake (Irkutsk region): comparison with the therapeutic mud of the world [Electronic resource] / T.A. Yasnygina, S.V. Rasskazov, E.P. Chebykin, T.S. Fileva1,
E.V. Saranina, Yi-min Sun // Geology and Environment.— 2022.— V. 2, No. 1.— P. 84–109. DOI 10.26516/2541-9641.2022.1.84
Access Mode: http://geoenvir.ru/archive/g&e22-2-1/yasnygina22-1.htm (31.03.2022).